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An experiment was conducted with a direct injection Diesel engine operated with neat dimethyl ether (DME). Main focus of this research is to investigate the performance of the catalysts designed for NOx reduction, such as Co–alumina and Sn–alumina catalysts, for the reduction of NOX and other unburned species contained in the exhaust gas. In the experiments, DME concentration in the exhaust gas was changed by adding extra DME before the catalytic reactor, which is the important experimental parameter in the research. Results showed that NOX reduction rate was not so high without any DME addition, because the content of unburned DME, reducing agent, is very low in the DME engine exhaust gas. However, NOX reduction rate increased with increase in DME content and it reached around 80% with enough DME addition. The NOX reduction rate increased with increase in reaction temperature up to around 300 °C.

Changes in exhaust gas emissions during starting in a DI diesel engine were investigated. The THC after starting increased until around the 50th cycle when the fuel deposited on the combustion chamber showed the maximum, and THC then decreased to reach a steady value after about 1000 cycles when the piston wall temperature became constant. The NOx showed an initial higher peak just after starting, and increased to a steady value after about 1000 cycles. Exhaust odor had a strong correlation with THC, and at the early stage odor was stronger than would be expected from the THC concentration. The THC increased with increased fuel injection amounts, decreased cranking speeds, and fuels with higher viscosity, higher 90% distillation temperature, and lower ignitability.

To reduce NOx emissions from diesel engines, the urea-SCR (selective catalytic reduction) system has been introduced commercially. In urea-SCR, the freezing point of the urea aqueous solution, the deoxidizer, is −11°C, and the handling of the deoxidizer under cold weather conditions is a problem. Further, the ammonia escape from the catalyst and the generation of N2O emissions are also problems. To overcome these disadvantages of the urea-SCR system, the addition of a hydrocarbon deoxidizer has attracted attention. In this paper, a micro-reactor SCR system was developed and attached to the exhaust pipe of a single cylinder diesel engine. With the micro-reactor, the catalyst temperature, quantity of deoxidizer, and the space velocity can be controlled, and it is possible to use it with gas and liquid phase deoxidizers. The catalyst used in the tests reported here is Ag(1wt%)-γAl2O3.

Dual fuel combustion with premixed natural gas as the main fuel and diesel fuel as the ignition source was investigated in a 0.83 L, single cylinder, DI diesel engine. At low loads, increasing the equivalence ratio of natural gas to around 0.5 with intake throttling makes it possible to reduce the THC and CO emissions as well as to improve the thermal efficiency. At high loads, increasing the boost pressure moderates the combustion, but increases the THC and CO emissions, resulting in deterioration of the thermal efficiency. The EGR is essential to suppress the rapid combustion. As misfiring occurs with a compression ratio of 14.5 and there is excessively rapid combustion with 18.5 compression ratio, 16.5 is a suitable compression ratio.